MARC ayrıntıları
| 000 -LEADER |
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| fixed length control field |
08172nam a2200301 i 4500 |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION |
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| fixed length control field |
100419s2010 enka b 001 0 eng |
| 010 ## - LIBRARY OF CONGRESS CONTROL NUMBER |
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| LC control number |
2010013108 |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER |
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| International Standard Book Number |
9780470725436 |
| Qualifying information |
cloth |
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| International Standard Book Number |
0470725435 |
| Qualifying information |
cloth |
| 035 ## - SYSTEM CONTROL NUMBER |
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| System control number |
(OCoLC)608294940 |
| 040 ## - CATALOGING SOURCE |
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| Original cataloging agency |
DLC |
| Language of cataloging |
eng |
| Transcribing agency |
DLC |
| Modifying agency |
YDX |
| -- |
YDXCP |
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BWK |
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UKM |
| -- |
BWX |
| Description conventions |
rda |
| 049 ## - LOCAL HOLDINGS (OCLC) |
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| Holding library |
BAUN_MERKEZ |
| 050 04 - LIBRARY OF CONGRESS CALL NUMBER |
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| Classification number |
QD411 |
| Item number |
.L44 2010 |
| 082 00 - DEWEY DECIMAL CLASSIFICATION NUMBER |
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| Edition number |
22 |
| 100 1# - MAIN ENTRY--PERSONAL NAME |
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| Personal name |
Lee, Vladimir Ya |
| 245 10 - TITLE STATEMENT |
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| Title |
Organometallic compounds of low-coordinate Si, Ge, Sn, and Pb : |
| Remainder of title |
from phantom species to stable compounds / |
| Statement of responsibility, etc |
Vladimir Ya. Lee and Akira Sekiguchi |
| 264 #1 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE |
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| Place of production, publication, distribution, manufacture |
Chichester, West Sussex, U.K. : |
| Name of producer, publisher, distributor, manufacturer |
Wiley, |
| Date of production, publication, distribution, manufacture, or copyright notice |
2010. |
| 300 ## - PHYSICAL DESCRIPTION |
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| Extent |
xvi, 431 pages : |
| Other physical details |
illustrations ; |
| Dimensions |
25 cm |
| 336 ## - CONTENT TYPE |
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| Content Type Term |
text |
| Content Type Code |
txt |
| Source |
rdacontent |
| 337 ## - MEDIA TYPE |
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| Media Type Term |
unmediated |
| Media Type Code |
unmediated |
| Source |
rdamedia |
| 338 ## - CARRIER TYPE |
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| Carrier Type Term |
volume |
| Carrier Type Code |
volume |
| Source |
rdacarrier |
| 504 ## - BIBLIOGRAPHY, ETC. NOTE |
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| Bibliography, etc |
Includes bibliographical references and index |
| 505 00 - FORMATTED CONTENTS NOTE |
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| Title |
Contents |
| -- |
Preface |
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Abbreviations |
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1 Heavy Analogs of Carbenium Ions: Si-, Ge-, Sn- and Pb-Centered Cations |
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1.1 Introduction |
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1.2 Synthesis of RR'R"E+ Cations (E = Si-Pb) |
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1.2.1 From Halides RR'R"EX |
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1.2.2 From Hydrides RR'R"EH |
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1.2.3 From RR'R"E-R" and RR'R"E-ERR'R" |
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1.2.4 From Heavy Carbene Analogs RR'E |
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1.2.5 From Free Radicals RR'R"E |
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1.3 Reactions and Synthetic Applications of RR'R"E+ Cations16 |
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1.4 Theoretical Studies |
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1.4.1 Structure of Cations |
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1.4.2 Stability of Cations |
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1.4.3 Calculation of the NMR Chemical Shift of Cations |
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1.4.3.1 29Si NMR Chemical Shift Calculations |
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1.4.3.2 119Sn NMR Chemical Shift Calculations |
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1.5 Early Studies of RR'R"E+ Cations: Free or Coordinated? |
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1.6 Stable RR'R"E+ Cations |
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1.6.1 Intramolecularly Stabilized (Coordinated) Cations |
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1.6.2 Free (Noncoordinated) Cations |
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1.6.2.1 Cyclic π-Conjugated Cations |
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1.6.2.2 Acyclic Cations Lacking π-Conjugation 90 |
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1.7 Summary and Outlook |
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1.8 References |
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2 Heavy Analogs of Organic Free Radicals: Si-, Ge-, Sn-and Pb-Centered Radicals |
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2.1 Introduction |
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2.2 Early Studies: Transient Species RR'R"E |
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2.2.1 Generation |
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2.2.2 Structure (Identification) |
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2.2.2.1 Electronic Spectroscopy |
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2.2.2.2 EPR and CIDNP Spectroscopy |
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2.2.2.2.1 EPR Spectroscopy |
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2.2.2.3 Theoretical Calculations |
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2.2.3 Synthetic Applications |
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2.3 Persistent Radicals (Generation and Identification) |
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2.4 Stable Radicals |
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2.4.1 Neutral Radicals |
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2.4.1.1 Cyclic Radicals |
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2.4.1.2 Acyclic Tricoordinate Radicals |
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2.4.2 Charged Radicals |
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2.4.2.1 Anion-radicals |
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2.4.2.1.1 Cyclic Anion-radicals |
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2.4.2.1.2 Acyclic Anion-radicals |
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2.4.2.1.2.1 Heavy Carbenes Anion-radicals |
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2.4.2.1.2.2 Heavy Alkenes Anion-radicals |
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2.4.2.1.2.3 Heavy Alkynes Anion-radicals |
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2.4.2.2 Cation-radicals |
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2.4.3 Stable Biradicals of the Heavy Group 14 Elements |
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2.5 Summary and Outlook |
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2.6 References |
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3 Heavy Analogs of Carbanions: Si-, Ge-, Sn-and Pb-Centered Anions |
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3.1 Introduction |
| -- |
3.2 Synthesis |
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3.2.1 Alkyl-substituted Silyl Anions |
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3.2.2 Aryl-substituted Silyl Anions |
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3.2.3 Silyl-substituted Silyl Anions |
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3.2.4 Silyl Anions with Functional Groups |
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3.2.4.1 (Hydrido)Silyllithium Derivatives |
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3.2.4.2 (Halo)Silyllithium Derivatives |
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3.2.4.3 (Amino)Silyllithium Derivatives |
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3.2.4.4 (Alkoxy)Silyllithium Derivatives |
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3.2.4.5 (Acyl)Silyllithium Derivatives (Lithium Sila-enolates) |
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3.2.5 Cyclic Anions |
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3.2.5.1 Silole, Germole and Stannole Anions and Dianions |
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3.2.5.2 Cyclic Oligosilyl Anions |
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3.2.6 Polylithiosilanes |
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3.2.6.1 Tetralithiosilane |
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3.2.6.2 1, 1-Dilithiosilane Derivatives |
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3.2.6.3 1, 2-Dilithiodisilane Derivatives |
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3.2.6.4 1, 3-Dilithiotrisilane and 1, 4-Dilithiotetrasilane Derivatives |
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3.3.7 Germyl, Stannl and Plumbyl Anions |
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3.3 Structure |
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3.3.1 NMR Spectroscopy (Condensed Phase Structure) |
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3.3.2 X-ray Crystallography (Crystal Structure) |
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3.4 Reactions and Synthetic Applications |
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3.5 Recent Developments |
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3.5.1 sp3 Anions |
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3.5.2 sp2 Anions |
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3.5.3 Cyclic and Polycyclic Anions |
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3.6 Summary and Outlook |
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3.7 References |
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4 Heavy Analogs of Carbenes: Silylenes, Germylenes, Stannylenes and Plumbylenes |
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4.1 Introduction |
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4.2 Generation |
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4.2.1 Photolysis of Acyclic Oligo-and Polymetallanes |
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4.2.2 Photolysis of Cyclic Metallanes |
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4.2.3 Thermolysis of Oligo-and Monometallanes |
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4.2.4 α-Elimination of Silylenoids |
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4.2.5 Heavy Alkene-Heavy Carbene Rearrangements |
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4.3 Spectroscopic Identification |
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4.4 Structure |
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4.4.1 Multiplicity: Singlet vs Triplet |
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4.4.2 Substituent Effects |
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4.5 Reactions of Transient Species |
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4.5.1 Insertion into Single Bonds |
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4.5.2 Addition to Multiple Bonds |
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4.5.2.1 Addition to Alkenes |
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4.5.2.2 Addition to Alkynes |
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4.5.2.3 Addition to 1, 3-Dienes |
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4.5.3 Disilenes/Silenes from Silylenes: Dimerization, Rearrangement |
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4.5.4 Complexation to Transition Metals |
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4.6 Stable/Persistent Silylenes, Germylenes, Stannylenes and Plumbylenes |
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4.6.1 Singlet Species |
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4.6.1.1 Silylenes |
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4.6.1.2 Germylenes |
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4.6.1.3 Stannylenes |
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4.6.1.4 Plumbylenes |
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4.6.2 Triplet Species: Generation and Identification |
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4.7 Summary and Outlook |
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4.8 References |
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5 Heavy Analogs of Alkenes, 1, 3-Dienes, Allenes and Alkynes: Multiply Bonded Derivatives of Si, Ge, Sn and Pb |
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5.1 Introduction |
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5.2 Early Studies: Generation and Identification |
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5.3 Stable Derivatives (Synthesis and Structure) |
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5.3.1 Heavy Analogs of Alkenes (including cyclic compounds) |
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5.3.1.1 Homonuclear Compounds |
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5.3.1.1.1 Disilenes >Si=Si<3c-e, 12 |
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5.3.1.1.2 Digermenes>Ge=Ge<5c, 71 |
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5.3.1.1.3 Distannenes>Sn=Sn<5c, 71b, d |
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5.3.1.1.4 Diplumbenes>Pb=Pb<5c, 71d |
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5.3.1.2 Heteonuclear Compounds |
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5.3.1.2.1 Group 14/Group 14 Combinations: >E14 = E14'< (E14, E14' = C, Si, Ge, Sn, Pb) |
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5.3.1.2.1.1 Silenes>Si=C<124 |
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5.3.1.2.1.2 Germenes >Ge=C<71a, c, 124f, i |
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5.3.1.2.1.3 Stannenes >Sn=C<71b, 124f, i |
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5.3.1.2.1.4 Plumbenes >Pb=C<5a |
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5.3.1.2.1.5 Silagermenes >Si=Ge<124i |
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5.3.1.2.1.6 Silastannes >Si=Sn<124i |
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5.3.1.2.1.7 Germastannenes >Ge=Sn<124i |
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5.3.1.2.2 Group 14/Group 13 Combinations: >E14 = E13- (E14 = Si, Ge; E13 = B, Ga, In) |
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5.3.1.2.3 Group 14/Group 15 Combinations: <E14 = E15- (E14 = Si, Ge, Sn; E15 = N, P, As) |
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5.3.1.2.3.1 Silaimines >Si=N-179 |
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5.3.1.2.3.2 Germaimines >Ge=N-71a, c, 191a, b |
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5.3.1.2.3.3 Stannaimines >Sn=N-71b, 191a |
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5.3.1.2.3.4 Phosphasilenes >Si=P-203 |
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5.3.1.2.3.5 Phosphagermenes >Ge=P-71a-c, 191a |
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5.3.1.2.3.6 Phosphastannenes >Sn=P-71b, 191a |
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5.3.1.2.3.7 Arsasilenes >Si=As-217 |
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5.3.1.2.4 Group 14/Group 16 Combinations >E14 = E16 (E14 = Si, Ge, Sn; E16 = O, S, Se, Te) |
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5.3.1.2.4.1 >E14=O Combinations |
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5.3.1.2.4.2 >E14=S Combinations |
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5.3.1.2.4.3 >E14=Se Combinations |
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5.3.1.2.4.4 >E14=Te Combinations |
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5.3.2 Heavy Analogs of 1, 3-Dienes and Allenes |
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5.3.2.1 Heavy Analogs of 1, 3-Dienes 237 |
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5.3.2.2 Heavy Analogs of Allenes245 |
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5.3.3 Heavy Analogs of Alkynes: Disilynes, Digermynes, Distannynes, Diplumbynes, and their Valence Isomers260 |
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5.3.3.1 Disilynes RSiSiR |
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5.3.3.2 Digermynes RGeGeR (and their Valence Isomers) |
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5.3.3.3 Valence Isomers of Distannynes RSnSnR |
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5.3.3.4 Valence Isomers of Diplumbynes RpbPbR |
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5.3.3.5 Heavy Analogs of Alkynes: Structure and Bonding |
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5.4 Summary and Outlook |
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5.5 References |
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6 Heavy Analogs of Aromatic Compounds |
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6.1 Introduction |
| -- |
6.2 Early Studies |
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6.2.1 Transient Species: Generation, Identification and Trapping |
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6.3 Stable Compounds (Synthesis and Structure) |
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6.3.1 2π-Electron Species |
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6.3.1.1 Cyclopropenylium Ion Derivatives |
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6.3.1.2 Cyclobutadiene Dication Derivatives |
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6.3.2 6π-Electron Species |
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6.3.2.1 Benzene (and its Homologs) Derivatives |
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6.3.2.1.1 Theoretical Studies |
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6.3.2.1.2 Experimental Accomplishments |
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6.3.2.2 Cyclopentadienide Ion Derivatives |
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6.3.2.3 Cyclobutadiene Dianion Derivatives |
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6.3.2.4 Cycloheptatrienylium (Tropylium) Ion Derivatives |
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6.3.3 Homoaromaticity |
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6.3.4 Antiaromaticity |
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6.3.4.1 Cyclobutadiene Derivatives |
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6.3.4.2 Cyclopropenyl Anion Derivatives |
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6.3.4.3 Cyclopentadienylium Ion Derivatives |
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6.3.5 Reactivity of Heavy Aromatics: Complexation to Transition Metals |
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6.4 Summary and Outlook |
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6.5 References |
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Index |
| 650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM |
|---|
| Topical term or geographic name as entry element |
Organometallic compounds |
| 700 1# - ADDED ENTRY--PERSONAL NAME |
|---|
| Personal name |
Sekiguchi, Akira, |
| Dates associated with a name |
1952- |
| 900 ## - EQUIVALENCE OR CROSS-REFERENCE-PERSONAL NAME [LOCAL, CANADA] |
|---|
| Personal Name |
34804 |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) |
|---|
| Source of classification or shelving scheme |
Library of Congress Classification |
| Koha item type |
Kitap |
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