TY  - BOOK
AU  - Fink,Johannes Karl
TI  - Physical chemistry in depth
AV  - QD453 .F565 2009
PY  - 2009///
CY  - Heidelberg, New York
PB  - Springer
KW  - Chemistry, Physical and theoretical
N1  - Includes bibliographical references and index; -- Chapter 1: Mathematics of Thermodynamics; -- Some Properties of Special Functions; -- Functional Dependence; -- Change of the Arguments; -- Total Differential; -- Chain Rule; -- Substantial Derivative; -- Conversion of Differentials; -- Legendre Transformation; -- Law of Schwarz; -- Pfaffian Forms; -- Differentials of Functions; -- Euler's Theorem; -- Series; -- Analysis; -- Coordinate Systems; -- Chapter 2: Foundations of Thermodynamics; -- Idealization; -- Energy; -- Energy Forms; -- Energy Representation; -- System; -- Conservation Laws; -- Process; -- Transformers; -- Reservoir; -- Constraint Makers; -- Fundamental Equations; -- Partial Quantities; -- Thermodynamic Derivatives; -- Thermodynamic Similarity; -- Gibbs - Duhem Equations; -- The Principle of Finite Energy; -- The Minimum Energy Principle; -- Energy of a Quadratic Form; -- Maximum of Entropy; -- Coupled Energy Forms; -- Dimensionless Relative Variables; -- Stability; -- Phases; -- Chapter 3: The Laws of Thermodynamics; -- Zeroth Law of Thermodynamics; -- First Law of Thermodynamics; -- Second Law of Thermodynamics; -- Third Law of Thermodynamics; -- Chapter 4: Equations of State; -- The Ideal Gas; -- Internal Pressure; -- The van der Waals Gas; -- Incompressible Body; -- Corresponding States; -- Chapter 5: Thermodynamic Processes; -- Mechanical Heat Equivalent; -- Buoyancy; -- Processes in the Electric Field; -- Isentropic Process; -- Changes of Energy with Matter; -- Isothermal Process; -- Isodynamic Process; -- Joule Thomson Process; -- Chapter 6: Equilibrium; -- Energy and Entropy Formulation; -- Mechanical and chemical Equilibrium; -- Isodynamic and Equilibrium Processes; -- Setting Up the Equations for Equilibrium; -- Thermodynamic Functions; -- Diffusion Equilibria of Gases; -- A Glance on the Constraint Equations; -- Barometric Formula; -- Phase Transition Points; -- Colligative Properties; -- Isopiestics; -- Equilibrium of Distillation; -- Unlike Energy Forms; -- Chapter 7: The Phase Rule; -- A Schematic Phase Diagram; -- The Concept of Freedom; -- Derivation of the Phase Rule; -- Maximum Number of Phases; -- Eulers Polyhedral Formula; -- Polyhedral Formula and Phase Rule; -- Chapter 8: Troutons Rule; -- Dimensionless Variables; -- Phase Equilibrium; -- Chapter 9: Thermodynamic Cycles; -- Thermodynamic Cycles Have Edges; -- Chapter 10: Thermodynamic Paradoxes; -- Gibbs Paradox; -- Maxwell - Boltzmann Paradox; -- Maxwells Demon; -- Loschmidts Paradox; -- Thermodynamic Inequalities; -- Chemical Vapor Deposition; -- The Thermodynamics of Black Holes; -- The Perpetuum Mobile; -- Negative Heat Capacities; -- Expansion of an Incompressible Body; -- Fixing the Extensive Variables; -- Changes in Chemical Potential and Pressure; -- Chapter 11: Dimensional Analysis; -- Units; -- The Minimal Set of Basic Fundamental Units; -- The Nature of a Physical Quantity; -- Illustrative Examples; -- Chapter 12: Generating Functions; -- Computation of Probabilities; -- Computation of the Number of Isomers; -- Calculation of Isotopic Patterns; -- Forms of Generating Functions; -- Solution of Systems of Differential Equations; -- Statistical Thermodynamics; -- Adsorption Isotherms; -- Chapter 13: Stoichiometry; -- Half-Reaction Method; -- Balancing by Inspection; -- A Challenging Balance; -- Balancing with Generating Functions; -- Further Examples; -- Chapter 14: Nomenclature; -- Nomenclature Systems; -- A Nomenclature for Simple Chemicals; -- Machine-Readable Representations; -- File Formats; -- Chemical Markup Language; -- Molecules as Graphs; -- Chapter 15: Symmetry; -- Noethers Symmetry Theorem; -- Group Theory; -- Stereochemistry; -- Woodward - Hoffmann Rules; -- Chemical Kinetics; -- Dipole Moments; -- Mechanics; -- Thermodynamics; -- Crystallography; -- Biosciences; -- Chapter 16: Harmony; -- Tools of Harmony; -- Vibrating String; -- Particle in a Box; -- Fourier Transform Techniques; -- Chapter 17: Generating Functions in Polymer Science; -- Polymerization; -- Polycondensation; -- Degradation; -- Chapter 18: Chemical Kinetics; -- Formal Kinetics; -- Stochastic Nature of Chemical Kinetics; -- Mechanical - Chemical Analogy; -- Chapter 19: Transport Phenomena; -- The Equations of Continuity; -- Capillary Flow; -- Irreversible Thermodynamics; -- Chapter 20: Separation Science; -- Particle Motion in a Homogeneous Field; -- Charge Particle in a Quadrupole Field; -- The Filter as an Instrument in Analytical Chemistry; -- Alternating Regression in GC/MS; -- Chapter 21: Stochastic Processes; -- Ludo; -- Wiener or Brown Process; -- Generalization of the Formalism; -- Stochastic Motion; -- Related Differential Equations; -- Chapter 22: Structure - Property Relationships; -- Increments; -- Graph Theoretical Numbers; -- Chapter 23: Factorial Designs; -- Simplex Method; -- Monte Carlo Methods; -- General Rules for Setting Up a Design; -- Time Series
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