TY  - BOOK
AU  - Crabtree,Robert H.
TI  - The organometallic chemistry of the transition metals
SN  - 0471853062
AV  - QD172.T6 C73 1988
PY  - 1988///]
CY  - New York
PB  - Wiley
KW  - Organotransition metal compounds
N1  - "A Wiley-Interscience publication."; Includes bibliographies and index; Werner Complexes; -- The Trans Effect; -- Soft Versus Hard Ligands; -- The Crystal Field; -- The Ligand Field; -- Back Bonding; -- Electroneutrality; -- Types of Ligand; -- General Properties of Organometallic Complexes; -- The 18-Electron Rule; -- Limitations of the 18-Electron Rule; -- Electron Counting in Reactions; -- Oxidation State; -- Coordination Number and Geometry; -- Effects of Complexation; -- Differences Between Metals; -- Inner/Outer-Sphere Coordination; -- Metal Alkyls, Aryls, and Hydrides and Related [sigma]-Bonded Ligands; -- Transition Metal Alkyls and Aryls; -- Related [sigma]-Bonded Ligands; -- Metal Hydride Complexes; -- Sigma Complexes; -- Bond Strengths for Classical [sigma]-Bonding Ligands; -- Carbonyls, Phosphine Complexes, and Ligand Substitution Reactions; -- Metal Complexes of CO, RNC, CS, and NO; -- Phosphines as Ligands; -- Dissociative Substitution; -- The Associative Mechanism; -- Redox Effects, The I Mechanism, and Rearrangements in Substitution; -- Photochemical Substitution; -- Steric and Solvent Effects in Substitution; -- Complexes of [pi]-Bound Ligands; -- Alkene and Alkyne Complexes; -- Allyl Complexes; -- Diene Complexes; -- Cyclopentadienyl Complexes; -- Complexes of Arenes and Other Alicyclic Ligands; -- Metalacycles and Isoelectronic and Isolobal Replacement; -- Stability of Polyene and Polyenyl Complexes; -- Oxidative Addition and Reductive Elimination; -- Concerted Additions; -- S[subscript N]2 Reactions; -- Radical Mechanisms; -- Ionic Mechanisms; -- Reductive Elimination; -- [sigma]-Bond Metathesis
ER  -