000			10575nam a2200325 i 4500
001			25867
008			020926s2002 at a b 001 0 eng d
010			_a2001095848
020			_a0125920601
040			_aBGU _cBGU _dOSU _dBAUN
049			_aBAUN_MERKEZ
050	0	4	_aQD474 _b.R62 2002
100	1		_aRodgers, Glen E., _d1944-
245	1	0	_aDescriptive inorganic, coordination, and solid-state chemistry / _cGlen E. Rodgers
250			_a2nd ed
264		1	_a[Australia ; _bBrooks/Cole : _c[2002]
264		1	_aUnited States] : _bThomson Learning, _c[2002]
264		4	_c©2002
300			_axxii, 586 pages : _billustrations ; _c26 cm
336			_atext _btxt _2rdacontent
337			_aunmediated _bn _2rdamedia
338			_avolume _bnc _2rdacarrier
504			_aIncludes bibliographical references (pages 549-554) and index
505	0	0	_tThe Evolving Realm of Inorganic Chemistry _tSummary _tPart I Coordination Chemistry _tAn Introduction to Coordination Chemistry _tThe Historical Perspective _tThe History of Coordination Compounds _tEarly Compounds _tThe Blomstrand--Jørgensen Chain Theory _tThe Werner Coordination Theory _tThe Modern View of Coordination Compounds _tAn Introduction to the Nomenclature of Coordination Compounds _tSummary _tProblems _tStructures of Coordination Compounds _tStereoisomers _tOctahedral Coordination Spheres _tCompounds with Monodentate Ligands _tCompounds with Chelating Ligands _tSquare Planar Coordination Spheres _tTetrahedral Coordination Spheres _tOther Coordination Spheres _tStructural Isomers _tSummary _tProblems _tBonding Theories for Coordination Compounds _tEarly Bonding Theories _tThe Lewis Acid-Base Definition _tCrystal Field, Valence-Bond, and Molecular Orbital Theories _tCrystal Field Theory _tShapes of 3d Orbitals _tOctahedral Fields _tTetragonally Distorted Octahedral and Square Planar Fields _tTetrahedral Fields _tConsequences and Applications of Crystal Field Splitting _tCrystal Field Splitting Energies versus Pairing Energies _tCrystal Field Stabilization Energies _tFactors Affecting the Magnitude of the Crystal Field Splitting Energies _tMagnetic Properties _tAbsorption Spectroscopy and the Colors of Coordination Compounds _tSummary _tProblems _tRates and Mechanisms of Reactions of Coordination Compounds _tA Brief Survey of Reaction Types _tLabile and Inert Coordination Compounds _tSubstitution Reactions of Octahedral Complexes _tPossible Mechanisms _tExperimental Complications _tEvidence for Dissociative Mechanisms _tExplanation of Inert versus Labile Complexes _tRedox, or Electron Transfer, Reactions _tOuter-Sphere Mechanisms _tInner-Sphere Mechanisms _tSubstitution Reactions in Square Planar Complexes: The Kinetic Trans Effect _tSummary _tProblems _tApplications of Coordination Compounds _tApplications of Monodentate Complexes _tTwo Keys to the Stability of Transition Metal Complexes _tHard and Soft Acids and Bases _tThe Chelate Effect _tApplications of Multidentate Complexes _tChelating Agents as Detergent Builders _tBioinorganic Applications of Coordination Chemistry _tOxygen Transport _tTherapeutic Chelating Agents for Heavy Metals _tPlatinum Antitumor Agents _tSummary _tProblems _tPart II Solid-State Chemistry _tSolid-State Structures _tTypes of Crystals _tIonic Crystals _tMetallic Crystals _tCovalent Network Crystals _tAtomic-Molecular Crystals _tA Type Crystal Lattices _tSpace Lattices and Unit Cells _tA Type Lattices _tABn-Type Crystal Lattices _tCubic, Octahedral, and Tetrahedral Holes _tRadius Ratios _tIonic Radii _tAB Structures _tAB2 Structures _tStructures Involving Polyatomic Molecules and Ions _tDefect Structures _tSpinel Structures: Connecting Crystal Field Effects with Solid-State Structures _tSummary _tProblems _tSolid-State Energetics _tLattice Energy: A Theoretical Evaluation _tLattice Energy: Thermodynamic Cycles _tElectron Affinities _tHeats of Formation for Unknown Compounds _tThermochemical Radii _tLattice Energies and Ionic Radii: Connecting Crystal Field Effects with Solid-State Energetics _tSummary _tProblems _tPart III Descriptive Chemistry of the Representative Elements _tBuilding a Network of Ideas to Make Sense of the Periodic Table _tThe Periodic Law _tEffective Nuclear Charge _tAtomic Radii _tIonization Energy _tElectron Affinity _tElectronegativity _tThe Uniqueness Principle _tThe Small Size of the First Elements _tThe Increased Likelihood of Pi Bonding in the First Elements _tThe Lack of Availability of d Orbitals in the First Elements _tThe Diagonal Effect _tThe Inert-Pair Effect _tMetal, Nonmetal, and Metalloid Regions _tSummary _tProblems _tHydrogen and Hydrides _tThe Origin of the Elements (and of Us!) _tDiscovery, Preparation, and Uses of Hydrogen _tIsotopes of Hydrogen _tRadioactive Processes Involving Hydrogen _tAlpha and Beta Decay, Nuclear Fission, and Deuterium _tTritium _tHydrides and the Network _tCovalent Hydrides _tIonic Hydrides _tMetallic Hydrides _tThe Role of Hydrogen in Various Alternative Energy Sources _tThe Hydrogen Economy _tNuclear Fusion _tSummary _tProblems _tOxygen, Aqueous Solutions, and the Acid-Base Character of Oxides and Hydroxides _tOxygen _tDiscovery _tOccurrence, Preparation, Properties, and Uses _tWater and Aqueous Solutions _tThe Structure of the Water Molecule _tIce and Liquid Water _tSolubility of Substances in Water _tSelf Ionization of Water _tThe Acid-Base Character of Oxides and Hydroxides in Aqueous Solution _tOxides: General Expectations from the Network _tOxides in Aqueous Solution (Acidic and Basic Anhydrides) _tThe E-O-H Unit in Aqueous Solution _tAn Addition to the Network _tThe Relative Strengths of Oxoacids and Hydroacids in Aqueous Solution _tOxoacids _tNomenclature of Oxoacids and Corresponding Salts (Optional) _tHydroacids _tOzone _tThe Greenhouse Effect and Global Warming _tSummary _tProblems _tGroup 1A: The Alkali Metals _tDiscovery and Isolation of the Elements _tFundamental Properties and the Network _tHydrides, Oxides, Hydroxides, and Halides _tApplication of the Uniqueness Principle and Diagonal Effect _tReduction Potentials and the Network _tPeroxides and Superoxides _tPeroxides _tSuperoxides _tReactions and Compounds of Practical Importance _tSelected Topic in Depth: Metal-Ammonia Solutions _tSummary _tProblems _tGroup 2A: The Alkaline-Earth Metals _tDiscovery and Isolation of the Elements _tCalcium, Barium, and Strontium _tMagnesium _tBeryllium _tRadium _tFundamental Properties and the Network _tHydrides, Oxides, Hydroxides, and Halides _tUniqueness of Beryllium and Diagonal Relationship to Aluminum _tReactions and Compounds of Practical Importance _tBeryllium Disease _tRadiochemical Uses _tMetallurgical Uses _tFireworks and X Rays _tHard Water _tSelected Topic in Depth: The Commercial Uses of Calcium Compounds _tCaCO3 (Limestone) _tCaO (Quicklime) and Ca(OH)2 (Slaked Lime) _tSummary _tProblems _tThe Group 3A Elements _tDiscovery and Isolation of the Elements _tBoron _tAluminum _tGallium _tIndium and Thallium _tFundamental Properties and the Network _tHydrides, Oxides, Hydroxides, and Halides _tStructural Aspects of Boron Chemistry _tAllotropes _tBorides _tBorates _tAluminum, Gallium, Indium, and Thallium: Reactions and Compounds of Practical Importance _tAluminum Metal and Alloys _tAlums _tAlumina _tGallium, Indium, and Thallium Compounds _tSelected Topic in Depth: Electron-Deficient Compounds _tSummary _tProblems _tThe Group 4A Elements _tDiscovery and Isolation of the Elements _tCarbon, Tin, and Lead _tSilicon _tGermanium _tFundamental Properties and the Network _tHydrides _tOxides and Hydroxides _tHalides _tAn Eighth Component of the Interconnected Network: pπ-dπ Bonding Involving Elements of the Second and Third Periods _tReactions and Compounds of Practical Importance _tDiamond, Graphite, and the Graphenes _tTin Disease _tRadiochemical Uses _tCarbon Compounds _tLead Compounds and Toxicology _tSilicates, Silica, and Aluminosilicates _tSilicates and Silica _tAluminosilicates _tSelected Topics in Depth: Semiconductors and Glass _tSemiconductors _tGlass _tSummary _tProblems _tGroup 5A: The Pnicogens _tDiscovery and Isolation of the Elements _tAntimony and Arsenic _tPhosphorus _tBismuth _tNitrogen _tFundamental Properties and the Network _tThe Uniqueness Principle _tPπ-dπ Bonding Involving Elements of the Second and Third Periods _tOther Network Components _tHydrides _tOxides and Oxoacids _tHalides _tA Survey of Nitrogen Oxidation States _tNitrogen (-3) Compounds: Nitrides and Ammonia _tNitrogen (-2): Hydrazine, N2H4 _tNitrogen (-1): Hydroxylamine, NH2OH _tNitrogen (+1): Nitrous Oxide, N2O _tNitrogen (+2): Nitric Oxide, NO _tNitrogen (+3): Dinitrogen Trioxide, N2O3, and Nitrous Acid, HNO2 _tNitrogen (+4): Nitrogen Dioxide, NO2 _tNitrogen (+5): Dinitrogen Pentoxide, N2O5, and Nitric Acid, HNO3 _tReactions and Compounds of Practical Importance _tNitrogen Fixation _tNitrates and Nitrites _tNitrogen Air Bags _tMatches and Phossy Jaw _tPhosphates _tSelected Topic in Depth: Photochemical Smog _tSummary _tProblems _tSulfur, Selenium, Tellurium, and Polonium _tDiscovery and Isolation of
505	0	0	_t the Elements _tSulfur _tTellurium and Selenium (Earth and Moon) _tPolonium _tFundamental Properties and the Network _tHydrides _tOxides and Oxoacids _tHalides _tAllotropes and Compounds Involving Element-Element Bonds _tAllotropes _tPolycations and Anions _tCatenated Halides and Hydrides _tCatenated Oxoacids and Corresponding Salts _tSulfur Nitrides _tReactions and Compounds of Practical Importance _tSodium-Sulfur Batteries _tPhotoelectric Uses of Selenium and Tellurium _tSulfuric Acid _tSelected Topic in Depth: Acid Rain _tSummary _tProblems _tGroup 7A: The Halogens _tDiscovery and Isolation of the Elements _tChlorine _tIodine _tBromine _tFluorine _tAstatine _tFundamental Properties and the Network _tHydrides _tHalides _tOxides _tOxoacids and Their Salts _tHypohalous Acids, HOX, and Hypohalites, OX- _tHalous Acids, HOXO, and Halites, XO-2 _tHalic Acids, HOXO2, and Halates, XO-3 _tPerhalic Acids, HOXO3, and Perhalates, XO-4 _tNeutral and Ionic Interhalogens _tReactions and Compounds of Practical Importance _tFluoridation _tChlorination _tBleaches _tBromides _tSelected Topic in Depth: Chlorofluorocarbons (CFCs)-A Threat to the Ozone Layer _tSummary _tProblems _tGroup 8A: The Noble Gases _tDiscovery and Isolation of the Elements _tArgon _tHelium _tKrypton, Neon, and Xenon _tRadon _tFundamental Properties and the Network _tCompounds of Noble Gases _tHistory _tFluorides _tStructures _tOther Compounds _tPhysical Properties and Elements of Practical Importance _tSelected Topic in Depth: Radon as a Carcinogen _tSummary _tProblems _tA Word about Sources _tCredit References _tLists of Figures, Tables, Formulas, and Constants _tIndex
650		0	_aCoordination compounds
650		0	_aSolid state chemistry
650		0	_aChemistry, Inorganic
942			_2lcc _cKT
999			_c21325 _d21325