000 11941nam a2200349 i 4500
008 071004s2008 njua b 001 0 eng
010 _a2007041578
020 _a9780471732792
_qcloth
020 _a0471732796
_qcloth
035 _a(OCoLC)173809122
040 _aDLC
_beng
_cDLC
_dBAKER
_dBTCTA
_dUKM
_dC#P
_dYDXCP
_dBAUN
_erda
049 _aBAUN_MERKEZ
050 0 4 _aTA462
_b.R425 2008
082 0 0 _222
100 1 _aRevie, R. Winston
_q(Robert Winston),
_d1944-
245 1 0 _aCorrosion and corrosion control :
_ban introduction to corrosion science and engineering /
_cR. Winston Revie, Herbert H. Uhlig
250 _a4th ed
264 1 _aHoboken, N.J. :
_bWiley-Interscience,
_c[2008]
264 4 _c©2008
300 _axx, 490 pages :
_billustrations ;
_c25 cm
336 _atext
_btxt
_2rdacontent
337 _aunmediated
_bn
_2rdamedia
338 _avolume
_bnc
_2rdacarrier
504 _aIncludes bibliographical references and index
505 0 0 _t1. Definition and Importance of Corrosion.
_t1.1 Definition of Corrosion.
_tCorrosion Science and Engineering.
_t1.2 Importance of Corrosion.
_t1.3 Risk Management.
_t1.4 Causes of Corrosion.
_tChange in Gibbs Free Energy.
_tPilling-Bedworth Ratio.
_t1.5 References.
_t1.6 General References.
_t1.7 Problems.
_t2. Electrochemical Mechanisms.
_t2.1 The Dry-cell Analogy and Faraday’s Law.
_t2.2 Definition of Anode and Cathode.
_t2.3 Types of Cells.
_t2.4 Forms of Corrosion.
_t2.5 References.
_t2.6 General References.
_t2.7 Problems.
_t3. Thermodynamics: Corrosion Tendency and Electrode Potentials.
_t3.1 Change of Gibbs Free Energy, ?G.
_t3.2 Measuring the Emf of a Cell.
_t3.3 Calculating the Half-Cell Potential - The Nernst Equation .
_t3.4 The Hydrogen Electrode and Standard Hydrogen Scale.
_t3.5 Calculation of EMF.
_t3.6 Measurement of pH.
_t3.7 The Oxygen Electrode and Differential Aeration Cell.
_t3.8 The EMF and Galvanic Series.
_t3.9 Liquid Junction Potentials.
_t3.10 Reference Electrodes.
_tCalomel Reference Electrode.
_tSilver-Silver Chloride Reference Electrode.
_tSaturated Copper-Copper Sulfate Reference Electrode.
_t3.11 References.
_t3.12 General References.
_t3.13 Problems.
_t4. Thermodynamics: Pourbaix Diagrams.
_t4.1 Basis of Pourbaix Diagrams.
_t4.2 Pourbaix Diagram for Water.
_t4.3 Pourbaix Diagram for Iron.
_t4.4 Pourbaix Diagram for Aluminum.
_t4.5 Pourbaix Diagram for Magnesium.
_t4.6 Limitations of Pourbaix Diagrams.
_t4.7 References.
_t4.8 General Reference .
_t4.9 Problems.
_t5. Kinetics: Polarization and Corrosion Rates.
_t5.1 Polarization.
_t5.2 The Polarized Cell.
_t5.3 How Polarization Is Measured.
_tCalculation of IR Drop in an Electrolyte.
_t5.4 Causes of Polarization.
_t5.5 Hydrogen Overpotential.
_t5.6 Polarization Diagrams of Corroding Metals.
_t5.7 Influence of Polarization on Corrosion Rate.
_t5.8 Calculation of Corrosion Rates from Polarization Data.
_t5.9 Anode-Cathode Area Ratio.
_t5.10 Electrochemical Impedance Spectroscopy.
_t5.11 Theory of Cathodic Protection.
_t5.12 References.
_t5.13 General References.
_t5.14 Problems.
_t6. Passivity.
_t6.1 Definition.
_t6.2 Characteristics of Passivation and the Flade Potential.
_t6.3 Behavior of Passivators.
_tPassivation of Iron by HNO3.
_t6.4 Anodic Protection and Transpassivity.
_t6.5 Theories of Passivity.
_tMore Stable Passive Films with Time.
_tAction of Chloride Ions and Passive-Active Cells.
_tCritical Pitting Potential (CPP).
_t6.6 Critical Pitting Potential.
_t6.7 Critical Pitting Temperature .
_t6.8 Passivity of Alloys.
_tNickel-Copper Alloys.
_tOther Alloys.
_t6.9 Effect of Cathodic Polarization and Catalysis.
_t6.10 References.
_t6.11 General References.
_t6.12 Problems.
_t7. Iron and Steel.
_t7.1 Introduction.
_t7.2 Aqueous Environments.
_tEffect of Dissolved Oxygen.
_tAir-Saturated Water.
_tHigher Partial Pressures of Oxygen.
_tMicrobiologically Influenced Corrosion (MIC).
_tEffect of Temperature.
_tEffect of pH.
_tCorrosion of Iron in Acids.
_tEffect of Galvanic Coupling.
_tEffect of Velocity on Corrosion in Natural Waters.
_tCavitation-Erosion.
_tEffect of Dissolved Salts.
_tNatural-Water Salts.
_t7.3 Metallurgical Factors.
_tVarieties of Iron and Steel.
_tEffects of Composition.
_tGalvanic Effects through Coupling of Different Steels.
_tEffect of Heat Treatment.
_t7.4 Steel Reinforcements in Concrete.
_t7.5 References.
_t7.6 General References.
_t7.7 Problems.
_t8. Effect of Stress.
_t8.1 Cold Working.
_t8.2 Stress-Corrosion Cracking of Iron and Steel.
_t8.3 Mechanism of Stress-Corrosion Cracking of Steel and Other Metals.
_tElectrochemical Dissolution Theory.
_tStress-Sorption Cracking.
_tInitiation of Stress-Corrosion Cracking and Critical Potentials.
_tRate of Crack Growth (Fracture Mechanics).
_t8.4 Hydrogen Cracking.
_tMechanism of Hydrogen Cracking.
_tEffect of Metal Flaws.
_t8.5 Radiation Damage.
_t8.6 Corrosion Fatigue.
_tCritical Minimum Corrosion Rates.
_tRemedial Measures.
_tMechanism of Corrosion Fatigue.
_t8.7 Fretting Corrosion.
_tMechanism of Fretting Corrosion.
_tRemedial Measures.
_t8.8 References.
_t8.9 General References.
_t8.10 Problems.
_t9. Atmospheric Corrosion.
_t9.1 Introduction.
_t9.2 Types of Atmospheres.
_t9.3 Corrosion-Product Films.
_t9.4 Factors Influencing Corrosivity of the Atmosphere.
_tParticulate Matter.
_tGases in the Atmosphere.
_tMoisture (Critical Humidity).
_t9.5 Remedial Measures.
_t9.6 References.
_t9.7 General References.
_t9.8 Problems.
_t10. Corrosion in Soils .
_t10.1 Introduction.
_t10.2 Factors Affecting the Corrosivity of Soils.
_t10.3 Bureau of Standards Tests.
_tPitting Characteristics.
_t10.4 Stress-Corrosion Cracking.
_t10.5 Remedial Measures.
_t10.6 References.
_t10.7 General References.
_t11. Oxidation.
_t11.1 Introduction.
_t11.2 Initial Stages.
_t11.3 Thermodynamics of Oxidation: Free Energy-Temperature Diagram.
_t11.4 Protective and Nonprotective Scales.
_tThree Equations of Oxidation.
_t11.5 Wagner Theory of Oxidation.
_t11.6 Oxide Properties and Oxidation.
_t11.7 Galvanic Effects and Electrolysis of Oxides.
_t11.8 Hot Ash Corrosion.
_t11.9 Hot Corrosion.
_t11.10 Oxidation of Copper.
_tInternal Oxidation.
_tReaction with Hydrogen ("Hydrogen Disease").
_t11.11 Oxidation of Iron and Iron Alloys.
_t11.12 Life Test for Oxidation-Resistant Wires.
_t11.13 Oxidation-Resistant Alloys.
_tReactive Element Effect (REE).
_tChromium-Iron Alloys.
_tChromium-Aluminum-Iron Alloys.
_tNickel and Nickel Alloys.
_tFurnace Windings.
_t11.14 References.
_t11.15 General References.
_t11.16 Problems.
_t12. Stray-Current Corrosion.
_t12.1 Introduction.
_t12.2 Sources of Stray Current.
_t12.3 Quantitative Damage by Stray Currents.
_t12.4 Detection of Stray Currents.
_t12.5 Soil-Resistivity Measurement.
_t12.6 Means for Reducing Stray-Current Corrosion.
_t12.7 References.
_t12.8 General References.
_t12.9 Problems.
_t13. Cathodic Protection.
_t13.1 Introduction.
_t13.2 Brief History.
_t13.3 How Applied.
_tSacrificial Anodes.
_t13.4 Combined Use with Coatings.
_t13.5 Magnitude of Current Required.
_t13.6 Anode Materials and Backfill.
_tOverprotection.
_t13.7 Criteria of Protection.
_tPotential Measurements.
_tDoubtful Criteria.
_tPosition of Reference Electrode.
_t13.8 Economics of Cathodic Protection.
_t13.9 Anodic Protection.
_t13.10 References.
_t13.11 General References.
_t13.12 Problems.
_t14. Metallic Coatings.
_t14.1 Methods of Application.
_t14.2 Classification of Coatings.
_t14.3 Specific Metal Coatings.
_tNickel Coatings.
_tLead Coatings.
_tZinc Coatings.
_tCadmium Coatings.
_tTin Coatings.
_tChromium-Plated Steel for Containers.
_tAluminum Coatings.
_t14.4 References.
_t14.5 General References.
_t15. Inorganic Coatings.
_t15.1 Vitreous Enamels.
_t15.2 Portland Cement Coatings.
_t15.3 Chemical Conversion Coatings.
_t15.4 References.
_t15.5 General References.
_t16. Organic Coatings.
_t16.1 Introduction.
_t16.2 Paints.
_t16.3 Requirements for Corrosion Protection.
_t16.4 Metal Surface Preparation.
_tCleaning All Dirt, Oils, and Greases from the Surface.
_tComplete Removal of Rust and Mill Scale.
_t16.5 Applying Paint Coatings.
_tWash Primer.
_tPainting of Aluminum and Zinc.
_t16.6 Filiform Corrosion.
_tTheory of Filiform Corrosion.
_t16.7 Plastic Linings.
_t16.8 References.
_t16.9 General References.
_t17. Inhibitors and Passivators.
_t17.1 Introduction.
_t17.2 Passivators.
_tMechanism of Passivation.
_tApplications of Passivators.
_t17.3 Pickling Inhibitors.
_tApplications of Pickling Inhibitors.
_t17.4 Slushing Compounds.
_t17.5 Vapor-Phase Inhibitors.
_tInhibitor to Reduce Tarnishing of Copper.
_t17.6 References.
_t17.7 General References.
_t18. Treatment of Water and Steam Systems.
_t18.1 Deaeration and Deactivation.
_t18.2 Hot- and Cold-Water Treatment.
_tCooling Waters.
_t18.3 Boiler-Water Treatment.
_tBoiler Corrosion.
_tBoiler-Water Treatment for Corrosion Control.
_t18.4 References.
_t18.5 General References.
_t19.
505 0 0 _tAlloying for Corrosion Resistance; Stainless Steels.
_t19.1 Introduction.
_t19.2 Stainless Steels.
_tBrief History.
_tClasses and Types.
_tIntergranular Corrosion.
_tPitting and Crevice Corrosion.
_tStress-Corrosion Cracking and Hydrogen Cracking.
_tCracking of Sensitized Austenitic Alloys in Polythionic Acids.
_tGalvanic Coupling and General Corrosion Resistance.
_t19.3 References.
_t19.4 General References.
_t20. Copper and Copper Alloys.
_t20.1 Copper.
_tCorrosion in Natural Waters.
_t20.2 Copper Alloys.
_tCopper-Zinc Alloys (Brasses).
_tDezincification.
_tStress-Corrosion Cracking (Season Cracking).
_tCondenser Tube Alloys Including Copper-Nickel Alloys.
_t20.3 References.
_t20.4 General References.
_t20.5 Problems.
_t21. Aluminum and Aluminum Alloys.
_t21.1 Aluminum.
_tClad Alloys.
_tCorrosion in Water and Steam.
_tEffect of pH.
_tCorrosion Characteristics.
_tGalvanic Coupling.
_t21.2 Aluminum Alloys.
_tStress-Corrosion Cracking.
_t21.3 References.
_t21.4 General References .
_t22. Magnesium and Magnesium Alloys.
_t22.1 Introduction.
_t22.2 Magnesium.
_t22.3 Magnesium Alloys.
_tStress-Corrosion Cracking.
_tCoatings.
_t22.4 Summary.
_t22.5 References.
_t22.6 General References.
_t23. Nickel and Nickel Alloys.
_t23.1 Introduction.
_t23.2 Nickel.
_t23.3 Nickel Alloys.
_tGeneral Behavior.
_tNi-Cu System: Alloy 400 - 70% Ni, 30% Cu.
_tNi-Cr-Fe System: Alloy 600 - 76% Ni, 16% Cr, 7 0.000000e.
_tNi-Mo System: Alloy B - 60% Ni, 30% Mo, 5 0.000000e.
_tNi-Cr-Mo System: Alloy C - 54% Ni, 15% Cr, 16% Mo, 4% W, 5 0.000000e.
_t23.4 References.
_t23.5 General References.
_t24. Cobalt and Cobalt Alloys.
_t24.1 Introduction.
_t24.2 Cobalt Alloys.
_t24.3 References.
_t24.4 General References.
_t25. Titanium.
_t25.1 Titanium.
_t25.2 Titanium Alloys.
_t25.3 Pitting and Crevice Corrosion.
_t25.4 Intergranular Corrosion and Stress-Corrosion Cracking.
_t25.5 References.
_t25.6 General References.
_t25.7 Problem.
_t26. Zirconium.
_t26.1 Introduction.
_t26.2 Zirconium Alloys.
_t26.3 Behavior in Hot Water and Steam.
_t26.4 References.
_t26.5 General References.
_t27. Tantalum.
_t27.1 Introduction.
_t27.2 Corrosion Behavior.
_t27.3 References.
_t27.4 General References.
_t28. Lead.
_t28.1 Introduction.
_t28.2 Corrosion Behavior of Lead and Lead Alloys.
_tLead-Acid Battery.
_t28.3 Summary.
_t28.4 References.
_t28.5 General References.
_t29. Appendix.
_t29.1 Activity and Activity Coefficients of Strong Electrolytes.
_t29.2 Derivation of Stern-Geary Equation for Calculating Corrosion Rates from Polarization Data Obtained at Low Current Densities.
_t29.3 Derivation of Equation Expressing the Saturation Index of a Natural Water.
_t29.4 Derivation of Potential Change along a Cathodically Protected Pipeline.
_t29.5 Derivation of the Equation for Potential Drop along the Soil Surface Created by Current Entering or Leaving a Buried Pipe.
_t29.6 Derivation of the Equation for Determining Resistivity of Soil by Four-Electrode Method.
_t29.7 Derivation of the Equation Expressing Weight Loss by Fretting Corrosion.
_t29.8 Conversion Factors.
_tAdditional Conversion Factors.
_tCurrent Density Equivalent to a Corrosion Rate of 1 gmd.
_t29.9 Standard Potentials.
_t29.10 Notation and Abbreviations.
_t29.11 References.
_tIndex.
650 0 _aCorrosion and anti-corrosives
700 1 _aUhlig, Herbert Henry,
_d1907-
900 _a30838
900 _bsatın
942 _2lcc
_cKT
999 _c27637
_d27637