000 03343nam a2200337 i 4500
008 050615s2005 ne a 001 0 eng d
020 _a0415364213
_q(hardback)
020 _a0415364280
_q(student paperback)
035 _a.b59680787
040 _aEQO
_cEQO
_dBAKER
_dIAI
_dOSU
049 _aBAUN_MERKEZ
050 0 4 _aGB855
_b.A62 2005
100 1 _aAppelo, C. A. J
245 1 0 _aGeochemistry, groundwater and pollution /
_cC.A.J. Appelo, D. Postma
250 _a2nd ed
264 1 _aLeiden ;
_aNew York :
_bBalkema,
_c[2005]
264 4 _c©2005
300 _axviii, 649 pages :
_billustrations ;
_c25 cm
336 _atext
_btxt
_2rdacontent
337 _aunmediated
_bn
_2rdamedia
338 _avolume
_bnc
_2rdacarrier
504 _aIncludes bibliographical references and index
505 0 0 _tPreface
_t Contents
_t LIST OF EXAMPLES
_t NOTATION
_t 1 INTRODUCTION TO GROUNDWATER GEOCHEMISTRY
_t 1.1 Groundwater as drinking water
_t 1.1.1 Standards for drinking water
_t 1.2 Units of analysis
_t 1.3 Groundwater quality
_t 1.4 Sampling of groundwater
_t 1.4.1 Depth integrated or depth specific sampling
_t 1.4.2 Procedures for sampling of groundwater
_t 1.5 Chemical analysis of groundwater
_t 1.5.1 Field analyses and sample conservation
_t 1.5.2 Accuracy of chemical analysis
_t Problems
_t References
_t 2 FROM RAINWATER TO GROUNDWATER
_t 2.1 The hydrological cycle. 3.2.4 The aquifer as a chemical reactor3.3 Dating of groundwater
_t 3.4 Retardation
_t 3.4.1 The retardation equation
_t 3.4.2 Indifferent and broadening fronts
_t 3.4.3 Sharpening fronts
_t 3.4.4 Solid and solute concentrations
_t 3.5 Diffusion
_t 3.5.1 Diffusion coefficients
_t 3.5.2 Diffusion as a random process
_t 3.5.3 Diffusive transport
_t 3.5.4 Isotope diffusion
_t 3.6 Dispersion
_t 3.6.1 Column breakthrough curves
_t 3.6.2 Dispersion coefficients and dispersivity
_t 3.6.3 Macrodispersivity
_t Problems
_t References
_t 4 MINERALS AND WATER
_t 4.1 Equilibria and the solubility of minerals. 4.2 Corrections for solubility calculations4.2.1 Concentration and activity
_t 4.2.2 Aqueous complexes
_t 4.2.3 Combined complexes and activity corrections
_t 4.2.4 Calculation of saturation states
_t 4.3 Mass action constants and thermodynamics
_t 4.3.1 The calculation of mass action constants
_t 4.3.2 Calculation of mass action constants at different temperature
_t 4.4 Equilibrium calculations with PHREEQC
_t 4.4.1 Speciation calculations using PHREEQC
_t 4.4.2 The PHREEQC database
_t 4.4.3 Mineral equilibration
_t 4.5 Solid solutions
_t 4.5.1 Basic theory
_t 4.5.2 The fractionation factor for solid solutions. 4.5.3 Kinetic effects on the fractionation factor4.6 Kinetics of geochemical processes
_t 4.6.1 Kinetics and equilibrium
_t 4.6.2 Chemical reactions and rates
_t 4.6.3 Temperature dependency of reaction rates
_t 4.6.4 Mechanisms of dissolution and crystallization
_t 4.6.5 Rate laws for mineral dissolution and precipitation
_t Problems
_t References
_t 5 CARBONATES AND CARBON DIOXIDE
_t 5.1 Carbonate minerals
_t 5.2 Dissolved carbonate equilibria
_t 5.2.1 The carbonic acid system
_t 5.2.2 Determining the carbonate speciation in groundwater
_t 5.3 Carbon dioxide in soils
_t 5.4 Calcite solubility and PCO2.
650 0 _aWater chemistry
650 0 _aGroundwater
650 0 _aGroundwater
_xPollution
700 1 _aPostma, Dieke
900 _a31332
900 _bsatın
942 _2lcc
_cKT
999 _c28028
_d28028