000			08172nam a2200301 i 4500
008			100419s2010 enka b 001 0 eng
010			_a2010013108
020			_a9780470725436 _qcloth
020			_a0470725435 _qcloth
035			_a(OCoLC)608294940
040			_aDLC _beng _cDLC _dYDX _dYDXCP _dBWK _dUKM _dBWX _erda
049			_aBAUN_MERKEZ
050	0	4	_aQD411 _b.L44 2010
082	0	0	_222
100	1		_aLee, Vladimir Ya
245	1	0	_aOrganometallic compounds of low-coordinate Si, Ge, Sn, and Pb : _bfrom phantom species to stable compounds / _cVladimir Ya. Lee and Akira Sekiguchi
264		1	_aChichester, West Sussex, U.K. : _bWiley, _c2010.
300			_axvi, 431 pages : _billustrations ; _c25 cm
336			_atext _btxt _2rdacontent
337			_aunmediated _bn _2rdamedia
338			_avolume _bnc _2rdacarrier
504			_aIncludes bibliographical references and index
505	0	0	_tContents _t Preface _t Abbreviations _t1 Heavy Analogs of Carbenium Ions: Si-, Ge-, Sn- and Pb-Centered Cations _t1.1 Introduction _t1.2 Synthesis of RR'R"E+ Cations (E = Si-Pb) _t1.2.1 From Halides RR'R"EX _t1.2.2 From Hydrides RR'R"EH _t1.2.3 From RR'R"E-R" and RR'R"E-ERR'R" _t1.2.4 From Heavy Carbene Analogs RR'E _t1.2.5 From Free Radicals RR'R"E _t1.3 Reactions and Synthetic Applications of RR'R"E+ Cations16 _t1.4 Theoretical Studies _t1.4.1 Structure of Cations _t1.4.2 Stability of Cations _t1.4.3 Calculation of the NMR Chemical Shift of Cations _t1.4.3.1 29Si NMR Chemical Shift Calculations _t1.4.3.2 119Sn NMR Chemical Shift Calculations _t1.5 Early Studies of RR'R"E+ Cations: Free or Coordinated? _t1.6 Stable RR'R"E+ Cations _t1.6.1 Intramolecularly Stabilized (Coordinated) Cations _t1.6.2 Free (Noncoordinated) Cations _t1.6.2.1 Cyclic π-Conjugated Cations _t1.6.2.2 Acyclic Cations Lacking π-Conjugation 90 _t1.7 Summary and Outlook _t1.8 References _t2 Heavy Analogs of Organic Free Radicals: Si-, Ge-, Sn-and Pb-Centered Radicals _t2.1 Introduction _t2.2 Early Studies: Transient Species RR'R"E _t2.2.1 Generation _t2.2.2 Structure (Identification) _t2.2.2.1 Electronic Spectroscopy _t2.2.2.2 EPR and CIDNP Spectroscopy _t2.2.2.2.1 EPR Spectroscopy _t2.2.2.3 Theoretical Calculations _t2.2.3 Synthetic Applications _t2.3 Persistent Radicals (Generation and Identification) _t2.4 Stable Radicals _t2.4.1 Neutral Radicals _t2.4.1.1 Cyclic Radicals _t2.4.1.2 Acyclic Tricoordinate Radicals _t2.4.2 Charged Radicals _t2.4.2.1 Anion-radicals _t2.4.2.1.1 Cyclic Anion-radicals _t2.4.2.1.2 Acyclic Anion-radicals _t2.4.2.1.2.1 Heavy Carbenes Anion-radicals _t2.4.2.1.2.2 Heavy Alkenes Anion-radicals _t2.4.2.1.2.3 Heavy Alkynes Anion-radicals _t2.4.2.2 Cation-radicals _t2.4.3 Stable Biradicals of the Heavy Group 14 Elements _t2.5 Summary and Outlook _t2.6 References _t3 Heavy Analogs of Carbanions: Si-, Ge-, Sn-and Pb-Centered Anions _t3.1 Introduction _t3.2 Synthesis _t3.2.1 Alkyl-substituted Silyl Anions _t3.2.2 Aryl-substituted Silyl Anions _t3.2.3 Silyl-substituted Silyl Anions _t3.2.4 Silyl Anions with Functional Groups _t3.2.4.1 (Hydrido)Silyllithium Derivatives _t3.2.4.2 (Halo)Silyllithium Derivatives _t3.2.4.3 (Amino)Silyllithium Derivatives _t3.2.4.4 (Alkoxy)Silyllithium Derivatives _t3.2.4.5 (Acyl)Silyllithium Derivatives (Lithium Sila-enolates) _t3.2.5 Cyclic Anions _t3.2.5.1 Silole, Germole and Stannole Anions and Dianions _t3.2.5.2 Cyclic Oligosilyl Anions _t3.2.6 Polylithiosilanes _t3.2.6.1 Tetralithiosilane _t3.2.6.2 1, 1-Dilithiosilane Derivatives _t3.2.6.3 1, 2-Dilithiodisilane Derivatives _t3.2.6.4 1, 3-Dilithiotrisilane and 1, 4-Dilithiotetrasilane Derivatives _t3.3.7 Germyl, Stannl and Plumbyl Anions _t3.3 Structure _t3.3.1 NMR Spectroscopy (Condensed Phase Structure) _t3.3.2 X-ray Crystallography (Crystal Structure) _t3.4 Reactions and Synthetic Applications _t3.5 Recent Developments _t3.5.1 sp3 Anions _t3.5.2 sp2 Anions _t3.5.3 Cyclic and Polycyclic Anions _t3.6 Summary and Outlook _t3.7 References _t4 Heavy Analogs of Carbenes: Silylenes, Germylenes, Stannylenes and Plumbylenes _t4.1 Introduction _t4.2 Generation _t4.2.1 Photolysis of Acyclic Oligo-and Polymetallanes _t4.2.2 Photolysis of Cyclic Metallanes _t4.2.3 Thermolysis of Oligo-and Monometallanes _t4.2.4 α-Elimination of Silylenoids _t4.2.5 Heavy Alkene-Heavy Carbene Rearrangements _t4.3 Spectroscopic Identification _t4.4 Structure _t4.4.1 Multiplicity: Singlet vs Triplet _t4.4.2 Substituent Effects _t4.5 Reactions of Transient Species _t4.5.1 Insertion into Single Bonds _t4.5.2 Addition to Multiple Bonds _t4.5.2.1 Addition to Alkenes _t4.5.2.2 Addition to Alkynes _t4.5.2.3 Addition to 1, 3-Dienes _t4.5.3 Disilenes/Silenes from Silylenes: Dimerization, Rearrangement _t4.5.4 Complexation to Transition Metals _t4.6 Stable/Persistent Silylenes, Germylenes, Stannylenes and Plumbylenes _t4.6.1 Singlet Species _t4.6.1.1 Silylenes _t4.6.1.2 Germylenes _t4.6.1.3 Stannylenes _t4.6.1.4 Plumbylenes _t4.6.2 Triplet Species: Generation and Identification _t4.7 Summary and Outlook _t4.8 References _t5 Heavy Analogs of Alkenes, 1, 3-Dienes, Allenes and Alkynes: Multiply Bonded Derivatives of Si, Ge, Sn and Pb _t5.1 Introduction _t5.2 Early Studies: Generation and Identification _t5.3 Stable Derivatives (Synthesis and Structure) _t5.3.1 Heavy Analogs of Alkenes (including cyclic compounds) _t5.3.1.1 Homonuclear Compounds _t5.3.1.1.1 Disilenes >Si=Si<3c-e, 12 _t5.3.1.1.2 Digermenes>Ge=Ge<5c, 71 _t5.3.1.1.3 Distannenes>Sn=Sn<5c, 71b, d _t5.3.1.1.4 Diplumbenes>Pb=Pb<5c, 71d _t5.3.1.2 Heteonuclear Compounds _t5.3.1.2.1 Group 14/Group 14 Combinations: >E14 = E14'< (E14, E14' = C, Si, Ge, Sn, Pb) _t5.3.1.2.1.1 Silenes>Si=C<124 _t5.3.1.2.1.2 Germenes >Ge=C<71a, c, 124f, i _t5.3.1.2.1.3 Stannenes >Sn=C<71b, 124f, i _t5.3.1.2.1.4 Plumbenes >Pb=C<5a _t5.3.1.2.1.5 Silagermenes >Si=Ge<124i _t5.3.1.2.1.6 Silastannes >Si=Sn<124i _t5.3.1.2.1.7 Germastannenes >Ge=Sn<124i _t5.3.1.2.2 Group 14/Group 13 Combinations: >E14 = E13- (E14 = Si, Ge; E13 = B, Ga, In) _t5.3.1.2.3 Group 14/Group 15 Combinations: <E14 = E15- (E14 = Si, Ge, Sn; E15 = N, P, As) _t5.3.1.2.3.1 Silaimines >Si=N-179 _t5.3.1.2.3.2 Germaimines >Ge=N-71a, c, 191a, b _t5.3.1.2.3.3 Stannaimines >Sn=N-71b, 191a _t5.3.1.2.3.4 Phosphasilenes >Si=P-203 _t5.3.1.2.3.5 Phosphagermenes >Ge=P-71a-c, 191a _t5.3.1.2.3.6 Phosphastannenes >Sn=P-71b, 191a _t5.3.1.2.3.7 Arsasilenes >Si=As-217 _t5.3.1.2.4 Group 14/Group 16 Combinations >E14 = E16 (E14 = Si, Ge, Sn; E16 = O, S, Se, Te) _t5.3.1.2.4.1 >E14=O Combinations _t5.3.1.2.4.2 >E14=S Combinations _t5.3.1.2.4.3 >E14=Se Combinations _t5.3.1.2.4.4 >E14=Te Combinations _t5.3.2 Heavy Analogs of 1, 3-Dienes and Allenes _t5.3.2.1 Heavy Analogs of 1, 3-Dienes 237 _t5.3.2.2 Heavy Analogs of Allenes245 _t5.3.3 Heavy Analogs of Alkynes: Disilynes, Digermynes, Distannynes, Diplumbynes, and their Valence Isomers260 _t5.3.3.1 Disilynes RSiSiR _t5.3.3.2 Digermynes RGeGeR (and their Valence Isomers) _t5.3.3.3 Valence Isomers of Distannynes RSnSnR _t5.3.3.4 Valence Isomers of Diplumbynes RpbPbR _t5.3.3.5 Heavy Analogs of Alkynes: Structure and Bonding _t5.4 Summary and Outlook _t5.5 References _t6 Heavy Analogs of Aromatic Compounds _t6.1 Introduction _t6.2 Early Studies _t6.2.1 Transient Species: Generation, Identification and Trapping _t6.3 Stable Compounds (Synthesis and Structure) _t6.3.1 2π-Electron Species _t6.3.1.1 Cyclopropenylium Ion Derivatives _t6.3.1.2 Cyclobutadiene Dication Derivatives _t6.3.2 6π-Electron Species _t6.3.2.1 Benzene (and its Homologs) Derivatives _t6.3.2.1.1 Theoretical Studies _t6.3.2.1.2 Experimental Accomplishments _t6.3.2.2 Cyclopentadienide Ion Derivatives _t6.3.2.3 Cyclobutadiene Dianion Derivatives _t6.3.2.4 Cycloheptatrienylium (Tropylium) Ion Derivatives _t6.3.3 Homoaromaticity _t6.3.4 Antiaromaticity _t6.3.4.1 Cyclobutadiene Derivatives _t6.3.4.2 Cyclopropenyl Anion Derivatives _t6.3.4.3 Cyclopentadienylium Ion Derivatives _t6.3.5 Reactivity of Heavy Aromatics: Complexation to Transition Metals _t6.4 Summary and Outlook _t6.5 References _t Index
650		0	_aOrganometallic compounds
700	1		_aSekiguchi, Akira, _d1952-
900			_a34804
942			_2lcc _cKT
999			_c31983 _d31983