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008			151020s2011 njua b 001 0 eng d
010			_a2011283965
020			_a9789814366861 _q(paperback)
020			_a9814366862 _q(paperback)
020			_a9789814338752
020			_a9814338753
035			_a(OCoLC)739831025 _z(OCoLC)681485815 _z(OCoLC)729346862
040			_aSINUS _beng _cSINUS _dDLC _dBTCTA _dYDXCP _dMYG _dBWX _dCDX _dDEBBG _dUOH _dUPM _dVRC _dZWZ _dBAUN _erda
049			_aBAUN_MERKEZ
050	0	0	_aQD905.2 _b.D47 2011
082	0	0	_223
100	1		_aDesiraju, G. R. _q(Gautam R.) _992886 _eaut
245	1	0	_aCrystal engineering : _ba textbook / _cGautam R. Desiraju, Jagadese J Vittal, Arunachalam Ramanan.
264		1	_aHackensack, NJ : _bWorld Scientific : _bIISc Press, _c2011.
264		4	_c©2011.
300			_axiv, 216 pages : _billustrations ; _c28 cm.
336			_2rdacontent _atext _btxt
337			_2rdamedia _aunmediated _bn
338			_2rdacarrier _avolume _bnc
504			_aIncludes bibliographical references and index.
505	0	0	_t1.Crystal Engineering _t-- 1.1.X-ray Crystallography _t-- 1.2.Organic Solid State Chemistry _t-- 1.3.The Crystal as a Supramolecular Entity _t-- 1.4.Modern Crystal Engineering _t-- 1.4.1.Horizontal and Vertical Divisions of Chemistry _t-- 1.4.2.Organic Crystal Engineering _t-- 1.4.3.Metal-Organic Crystal Engineering _t-- 1.4.4.Properties of Crystals _t-- 1.5.Summary _t-- 1.6.Further Reading _t-- 1.7.Problems _t-- 2.Intermolecular Interactions _t-- 2.1.General Properties _t-- 2.2.Van Der Waals Interactions _t-- 2.2.1.Close Packing _t-- 2.3.Hydrogen Bonds _t-- 2.3.1.Weak Hydrogen Bonds _t-- 2.3.2.Hierarchies of Hydrogen Bonds _t-- 2.4.Halogen Bonds _t-- 2.5.Other Interactions _t-- 2.6.Methods of Study of Interactions _t-- 2.6.1.Crystallography _t-- 2.6.2.Crystallographic Databases _t-- 2.6.2.1.Graph Sets _t-- 2.6.3.Spectroscopy _t-- 2.6.4.Computational Methods _t-- 2.6.4.1.Crystal Structure Prediction _t-- 2.7.Analysis of Typical Crystal Structures _t-- 2.8.Summary _t-- 2.9.Further Reading _t-- 2.10.Problems _t-- 3.Crystal Design Strategies _t-- 3.1.Synthesis in Chemistry _t-- 3.2.Supramolecular Chemistry _t-- 3.3.The Synthon in Crystal Engineering _t-- 3.3.1.Some Representative Synthons _t-- 3.3.2.The Carboxyl Dimer Synthon _t-- 3.3.3.Structural Insulation in Crystal Engineering _t-- 3.3.4.Discovery of New Synthons _t-- 3.3.5.Two-dimensional Patterns _t-- 3.3.6.Higher Dimensional Control _t-- 3.3.7.Coordination Polymers as Networks _t-- 3.3.8.Useful Synthons _t-- 3.4.Summary _t-- 3.5.Further Reading _t-- 3.6.Problems _t-- 4.Crystallization and Crystal Growth _t-- 4.1.Crystallization of Organic Solids _t-- 4.1.1.Solution Crystallization _t-- 4.1.1.1.Antisolvent Crystallization _t-- 4.1.2.Melt Crystallization _t-- 4.1.3.Sublimation _t-- 4.1.4.Hydrothermal and Solvothermal Crystallization _t-- 4.1.5.Crystallization from a Solid Phase _t-- 4.1.5.1.Single Crystal to Single Crystal (SCSC) Transformations _t-- 4.1.5.2.Mechanochemistry _t-- 4.1.6.Crystallization of Chiral Solids _t-- 4.2.Nucleation _t-- 4.2.1.Nucleation as Distinct from Crystal Growth _t-- 4.3.Thermodynamics and Kinetics of Crystallization _t-- 4.4.Crystal Growth _t-- 4.4.1.The Terrace-Ledge-Kink Model of Crystal Growth _t-- 4.4.2.Two-dimensional Nucleation versus Growth at Dislocations _t-- 4.4.3.Ostwald Ripening _t-- 4.5.Crystal Morphology and Habit _t-- 4.5.1.Crystal Morphology and Crystal Symmetry _t-- 4.6.Crystal Morphology Engineering _t-- 4.6.1.Tailor-made Inhibitors _t-- 4.7.Why is it that all Compounds don't seem to Crystallize Equally Well or Equally Quickly? _t-- 4.8.Summary _t-- 4.9.Further Reading _t-- 4.10.Problems _t-- 5.Polymorphism _t-- 5.1.What is Polymorphism? _t-- 5.1.1.Polymorphism and the Pharmaceutical Industry _t-- 5.1.2.Some Simple Definitions _t-- 5.2.Occurrence of Polymorphism _t-- 5.2.1.Polymorphism and Intermolecular Interactions _t-- 5.3.Thermodynamics of Polymorphism _t-- 5.3.1.Free Energy Diagrams and Stability of Polymorphs _t-- 5.3.2.Monotropes and Enantiotropes _t-- 5.3.2.1.Burger-Ramberger Rules _t-- 5.3.2.2.Distinguishing between Enantiotropes and Monotropes _t-- 5.4.Thermodynamics versus Kinetics and the Fonnation of Polymorphs _t-- 5.5.Methods of Polymorph Characterization _t-- 5.5.1.Hot Stage Microscopy _t-- 5.5.2.X-ray Diffraction _t-- 5.5.3.Thermal Analysis _t-- 5.6.Properties of Polymorphs _t-- 5.6.1.Color _t-- 5.6.2.Mechanical Properties _t-- 5.6.3.Chemical Reactivity _t-- 5.6.3.1.Polymorphism in Energetic Materials _t-- 5.6.3.2.Polymorphism and Reactivity of Drugs _t-- 5.7.Case Studies from the Pharmaceutical Industry _t-- 5.7.1.Ranitidine _t-- 5.7.2.Ritonavir _t-- 5.7.3.Aspirin _t-- 5.7.4.Omeprazole _t-- 5.8.Polymorphism Today _t-- 5.9.Summary _t-- 5.10.Further Reading _t-- 5.11.Problems _t-- 6.Multi-component Crystals _t-- 6.1.General Classification and Nomenclature _t-- 6.2.Solid Solutions _t-- 6.3.Host-Guest Compounds _t-- 6.3.1.Design of Hosts _t-- 6.4.Solvates and Hydrates _t-- 6.5.Donor-Acceptor Complexes _t-- 6.6.Co-crystals _t-- 6.6.1.Hydrogen Bonded Co-crystals _t-- 6.6.2.Pharmaceutical Co-crystals _t-- 6.6.2.1.Design of Pharmaceutical Co-crystals _t-- 6.6.2.2.Properties of Pharmaceutical Co-crystals _t-- 6.6.2.3.Co-crystals and Salts _t-- 6.7.Summary _t-- 6.8.Further Reading _t-- 6.9.Problems _t-- 7.Coordination Polymers _t-- 7.1.What are Coordination Polymers? _t-- 7.2.Classification Schemes _t-- 7.3.Crystal Design Strategies _t-- 7.4.Network Topologies _t-- 7.4.1.Net Symbols and Nomenclature _t-- 7.4.2.Topologies of Three-dimensional Structures _t-- 7.4.2.1.Diamond Topology _t-- 7.4.2.2.NaCl Topology _t-- 7.4.2.3.NbO and CdSO4 Topologies _t-- 7.4.2.4.PtS and Related Topologies _t-- 7.5.Supramolecular Isomerism _t-- 7.6.Interpenetration _t-- 7.7.Porous Coordination Polymers _t-- 7.7.1.Pore Size _t-- 7.7.2.Gas Sorption and Storage _t-- 7.8.Properties and Applications _t-- 7.8.1.Magnetism, Magnetic Ordering and Spin Crossover _t-- 7.8.2.Luminescence and Sensing _t-- 7.8.3.Nonlinear Optical Properties _t-- 7.8.4.Proton Conductivity _t-- 7.8.5.Ferroelectricity _t-- 7.8.6.Birefringence _t-- 7.8.7.Negative Thermal Expansion _t-- 7.8.8.Processability _t-- 7.8.9.Chemical Reactivity _t-- 7.8.9.1.Structural Transformations on Heating _t-- 7.8.9.2.[2+2] Cycloaddition Reactions _t-- 7.8.9.3.Structural Transformations due to Loss of Solvents _t-- 7.8.9.4.Reactivity of Supramolecular Isomers _t-- 7.9.Building Approach: Influence of Experimental Conditions _t-- 7.10.Summary _t-- 7.11.Further Reading _t-- 7.12.Problems.
650		0	_aCrystallography _vTextbooks.
650		0	_aCrystal growth.
650		0	_aMolecular crystals.
700	1		_aVittal, Jagadese J.
700	1		_aRamanan, Arunachalam.
942			_2lcc _cKT
999			_c34459 _d34459