| 000 | 02629 am a2200325 i 4500 | ||
|---|---|---|---|
| 008 | 870721s1988 nyua b 001 0 eng | ||
| 010 | _a87021680 | ||
| 020 | _a0471853062 | ||
| 020 | _a9780471853060 | ||
| 020 | _a0471573884 | ||
| 020 | _a9780471573883 | ||
| 035 | _a(OCoLC) | ||
| 040 |
_aDLC _beng _cDLC _dUKM _dMUQ _dNLGGC _dBTCTA _dYDXCP _dOCLCG _dGEBAY _dJHY _dEXW _dOG# _dGBVCP _dOCLCF _dBAUN _erda |
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| 049 | _aBAUN_MERKEZ | ||
| 050 | 0 | 4 |
_aQD172.T6 _bC73 1988 |
| 100 | 1 |
_aCrabtree, Robert H., _d1948- _9103966 _eaut |
|
| 245 | 1 | 4 |
_aThe organometallic chemistry of the transition metals / _cRobert H. Crabtree. |
| 264 | 1 |
_aNew York : _bWiley, _c[1988] |
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| 264 | 4 | _c©1988 | |
| 300 |
_axv, 422 pages : _billustrations ; _c24 cm. |
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| 336 |
_2rdacontent _atext _btxt |
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| 337 |
_2rdamedia _aunmediated _bn |
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| 338 |
_2rdacarrier _avolume _bnc |
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| 500 | _a"A Wiley-Interscience publication." | ||
| 504 | _aIncludes bibliographies and index. | ||
| 505 | 0 | 0 |
_tWerner Complexes _t-- The Trans Effect _t-- Soft Versus Hard Ligands _t-- The Crystal Field _t-- The Ligand Field _t-- Back Bonding _t-- Electroneutrality _t-- Types of Ligand _t-- General Properties of Organometallic Complexes _t-- The 18-Electron Rule _t-- Limitations of the 18-Electron Rule _t-- Electron Counting in Reactions _t-- Oxidation State _t-- Coordination Number and Geometry _t-- Effects of Complexation _t-- Differences Between Metals _t-- Inner/Outer-Sphere Coordination _t-- Metal Alkyls, Aryls, and Hydrides and Related [sigma]-Bonded Ligands _t-- Transition Metal Alkyls and Aryls _t-- Related [sigma]-Bonded Ligands _t-- Metal Hydride Complexes _t-- Sigma Complexes _t-- Bond Strengths for Classical [sigma]-Bonding Ligands _t-- Carbonyls, Phosphine Complexes, and Ligand Substitution Reactions _t-- Metal Complexes of CO, RNC, CS, and NO _t-- Phosphines as Ligands _t-- Dissociative Substitution _t-- The Associative Mechanism _t-- Redox Effects, The I Mechanism, and Rearrangements in Substitution _t-- Photochemical Substitution _t-- Steric and Solvent Effects in Substitution _t-- Complexes of [pi]-Bound Ligands _t-- Alkene and Alkyne Complexes _t-- Allyl Complexes _t-- Diene Complexes _t-- Cyclopentadienyl Complexes _t-- Complexes of Arenes and Other Alicyclic Ligands _t-- Metalacycles and Isoelectronic and Isolobal Replacement _t-- Stability of Polyene and Polyenyl Complexes _t-- Oxidative Addition and Reductive Elimination _t-- Concerted Additions _t-- S[subscript N]2 Reactions _t-- Radical Mechanisms _t-- Ionic Mechanisms _t-- Reductive Elimination _t-- [sigma]-Bond Metathesis. |
| 650 | 0 |
_aOrganotransition metal compounds _9103967 |
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| 900 | _a450 | ||
| 942 |
_2lcc _cKT |
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| 999 |
_c3585 _d3585 |
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