MARC ayrıntıları
| 000 -LEADER |
| fixed length control field |
10575nam a2200325 i 4500 |
| 001 - CONTROL NUMBER |
| control field |
25867 |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION |
| fixed length control field |
020926s2002 at a b 001 0 eng d |
| 010 ## - LIBRARY OF CONGRESS CONTROL NUMBER |
| LC control number |
2001095848 |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER |
| International Standard Book Number |
0125920601 |
| 040 ## - CATALOGING SOURCE |
| Original cataloging agency |
BGU |
| Transcribing agency |
BGU |
| Modifying agency |
OSU |
| -- |
BAUN |
| 049 ## - LOCAL HOLDINGS (OCLC) |
| Holding library |
BAUN_MERKEZ |
| 050 04 - LIBRARY OF CONGRESS CALL NUMBER |
| Classification number |
QD474 |
| Item number |
.R62 2002 |
| 100 1# - MAIN ENTRY--PERSONAL NAME |
| Personal name |
Rodgers, Glen E., |
| Dates associated with a name |
1944- |
| 245 10 - TITLE STATEMENT |
| Title |
Descriptive inorganic, coordination, and solid-state chemistry / |
| Statement of responsibility, etc |
Glen E. Rodgers |
| 250 ## - EDITION STATEMENT |
| Edition statement |
2nd ed |
| 264 #1 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE |
| Place of production, publication, distribution, manufacture |
[Australia ; |
| Name of producer, publisher, distributor, manufacturer |
Brooks/Cole : |
| Date of production, publication, distribution, manufacture, or copyright notice |
[2002] |
|
| Place of production, publication, distribution, manufacture |
United States] : |
| Name of producer, publisher, distributor, manufacturer |
Thomson Learning, |
| Date of production, publication, distribution, manufacture, or copyright notice |
[2002] |
|
| Date of production, publication, distribution, manufacture, or copyright notice |
©2002 |
| 300 ## - PHYSICAL DESCRIPTION |
| Extent |
xxii, 586 pages : |
| Other physical details |
illustrations ; |
| Dimensions |
26 cm |
| 336 ## - CONTENT TYPE |
| Content Type Term |
text |
| Content Type Code |
txt |
| Source |
rdacontent |
| 337 ## - MEDIA TYPE |
| Media Type Term |
unmediated |
| Media Type Code |
unmediated |
| Source |
rdamedia |
| 338 ## - CARRIER TYPE |
| Carrier Type Term |
volume |
| Carrier Type Code |
volume |
| Source |
rdacarrier |
| 504 ## - BIBLIOGRAPHY, ETC. NOTE |
| Bibliography, etc |
Includes bibliographical references (pages 549-554) and index |
| 505 00 - FORMATTED CONTENTS NOTE |
| Title |
The Evolving Realm of Inorganic Chemistry |
| -- |
Summary |
| -- |
Part I Coordination Chemistry |
| -- |
An Introduction to Coordination Chemistry |
| -- |
The Historical Perspective |
| -- |
The History of Coordination Compounds |
| -- |
Early Compounds |
| -- |
The Blomstrand--Jørgensen Chain Theory |
| -- |
The Werner Coordination Theory |
| -- |
The Modern View of Coordination Compounds |
| -- |
An Introduction to the Nomenclature of Coordination Compounds |
| -- |
Summary |
| -- |
Problems |
| -- |
Structures of Coordination Compounds |
| -- |
Stereoisomers |
| -- |
Octahedral Coordination Spheres |
| -- |
Compounds with Monodentate Ligands |
| -- |
Compounds with Chelating Ligands |
| -- |
Square Planar Coordination Spheres |
| -- |
Tetrahedral Coordination Spheres |
| -- |
Other Coordination Spheres |
| -- |
Structural Isomers |
| -- |
Summary |
| -- |
Problems |
| -- |
Bonding Theories for Coordination Compounds |
| -- |
Early Bonding Theories |
| -- |
The Lewis Acid-Base Definition |
| -- |
Crystal Field, Valence-Bond, and Molecular Orbital Theories |
| -- |
Crystal Field Theory |
| -- |
Shapes of 3d Orbitals |
| -- |
Octahedral Fields |
| -- |
Tetragonally Distorted Octahedral and Square Planar Fields |
| -- |
Tetrahedral Fields |
| -- |
Consequences and Applications of Crystal Field Splitting |
| -- |
Crystal Field Splitting Energies versus Pairing Energies |
| -- |
Crystal Field Stabilization Energies |
| -- |
Factors Affecting the Magnitude of the Crystal Field Splitting Energies |
| -- |
Magnetic Properties |
| -- |
Absorption Spectroscopy and the Colors of Coordination Compounds |
| -- |
Summary |
| -- |
Problems |
| -- |
Rates and Mechanisms of Reactions of Coordination Compounds |
| -- |
A Brief Survey of Reaction Types |
| -- |
Labile and Inert Coordination Compounds |
| -- |
Substitution Reactions of Octahedral Complexes |
| -- |
Possible Mechanisms |
| -- |
Experimental Complications |
| -- |
Evidence for Dissociative Mechanisms |
| -- |
Explanation of Inert versus Labile Complexes |
| -- |
Redox, or Electron Transfer, Reactions |
| -- |
Outer-Sphere Mechanisms |
| -- |
Inner-Sphere Mechanisms |
| -- |
Substitution Reactions in Square Planar Complexes: The Kinetic Trans Effect |
| -- |
Summary |
| -- |
Problems |
| -- |
Applications of Coordination Compounds |
| -- |
Applications of Monodentate Complexes |
| -- |
Two Keys to the Stability of Transition Metal Complexes |
| -- |
Hard and Soft Acids and Bases |
| -- |
The Chelate Effect |
| -- |
Applications of Multidentate Complexes |
| -- |
Chelating Agents as Detergent Builders |
| -- |
Bioinorganic Applications of Coordination Chemistry |
| -- |
Oxygen Transport |
| -- |
Therapeutic Chelating Agents for Heavy Metals |
| -- |
Platinum Antitumor Agents |
| -- |
Summary |
| -- |
Problems |
| -- |
Part II Solid-State Chemistry |
| -- |
Solid-State Structures |
| -- |
Types of Crystals |
| -- |
Ionic Crystals |
| -- |
Metallic Crystals |
| -- |
Covalent Network Crystals |
| -- |
Atomic-Molecular Crystals |
| -- |
A Type Crystal Lattices |
| -- |
Space Lattices and Unit Cells |
| -- |
A Type Lattices |
| -- |
ABn-Type Crystal Lattices |
| -- |
Cubic, Octahedral, and Tetrahedral Holes |
| -- |
Radius Ratios |
| -- |
Ionic Radii |
| -- |
AB Structures |
| -- |
AB2 Structures |
| -- |
Structures Involving Polyatomic Molecules and Ions |
| -- |
Defect Structures |
| -- |
Spinel Structures: Connecting Crystal Field Effects with Solid-State Structures |
| -- |
Summary |
| -- |
Problems |
| -- |
Solid-State Energetics |
| -- |
Lattice Energy: A Theoretical Evaluation |
| -- |
Lattice Energy: Thermodynamic Cycles |
| -- |
Electron Affinities |
| -- |
Heats of Formation for Unknown Compounds |
| -- |
Thermochemical Radii |
| -- |
Lattice Energies and Ionic Radii: Connecting Crystal Field Effects with Solid-State Energetics |
| -- |
Summary |
| -- |
Problems |
| -- |
Part III Descriptive Chemistry of the Representative Elements |
| -- |
Building a Network of Ideas to Make Sense of the Periodic Table |
| -- |
The Periodic Law |
| -- |
Effective Nuclear Charge |
| -- |
Atomic Radii |
| -- |
Ionization Energy |
| -- |
Electron Affinity |
| -- |
Electronegativity |
| -- |
The Uniqueness Principle |
| -- |
The Small Size of the First Elements |
| -- |
The Increased Likelihood of Pi Bonding in the First Elements |
| -- |
The Lack of Availability of d Orbitals in the First Elements |
| -- |
The Diagonal Effect |
| -- |
The Inert-Pair Effect |
| -- |
Metal, Nonmetal, and Metalloid Regions |
| -- |
Summary |
| -- |
Problems |
| -- |
Hydrogen and Hydrides |
| -- |
The Origin of the Elements (and of Us!) |
| -- |
Discovery, Preparation, and Uses of Hydrogen |
| -- |
Isotopes of Hydrogen |
| -- |
Radioactive Processes Involving Hydrogen |
| -- |
Alpha and Beta Decay, Nuclear Fission, and Deuterium |
| -- |
Tritium |
| -- |
Hydrides and the Network |
| -- |
Covalent Hydrides |
| -- |
Ionic Hydrides |
| -- |
Metallic Hydrides |
| -- |
The Role of Hydrogen in Various Alternative Energy Sources |
| -- |
The Hydrogen Economy |
| -- |
Nuclear Fusion |
| -- |
Summary |
| -- |
Problems |
| -- |
Oxygen, Aqueous Solutions, and the Acid-Base Character of Oxides and Hydroxides |
| -- |
Oxygen |
| -- |
Discovery |
| -- |
Occurrence, Preparation, Properties, and Uses |
| -- |
Water and Aqueous Solutions |
| -- |
The Structure of the Water Molecule |
| -- |
Ice and Liquid Water |
| -- |
Solubility of Substances in Water |
| -- |
Self Ionization of Water |
| -- |
The Acid-Base Character of Oxides and Hydroxides in Aqueous Solution |
| -- |
Oxides: General Expectations from the Network |
| -- |
Oxides in Aqueous Solution (Acidic and Basic Anhydrides) |
| -- |
The E-O-H Unit in Aqueous Solution |
| -- |
An Addition to the Network |
| -- |
The Relative Strengths of Oxoacids and Hydroacids in Aqueous Solution |
| -- |
Oxoacids |
| -- |
Nomenclature of Oxoacids and Corresponding Salts (Optional) |
| -- |
Hydroacids |
| -- |
Ozone |
| -- |
The Greenhouse Effect and Global Warming |
| -- |
Summary |
| -- |
Problems |
| -- |
Group 1A: The Alkali Metals |
| -- |
Discovery and Isolation of the Elements |
| -- |
Fundamental Properties and the Network |
| -- |
Hydrides, Oxides, Hydroxides, and Halides |
| -- |
Application of the Uniqueness Principle and Diagonal Effect |
| -- |
Reduction Potentials and the Network |
| -- |
Peroxides and Superoxides |
| -- |
Peroxides |
| -- |
Superoxides |
| -- |
Reactions and Compounds of Practical Importance |
| -- |
Selected Topic in Depth: Metal-Ammonia Solutions |
| -- |
Summary |
| -- |
Problems |
| -- |
Group 2A: The Alkaline-Earth Metals |
| -- |
Discovery and Isolation of the Elements |
| -- |
Calcium, Barium, and Strontium |
| -- |
Magnesium |
| -- |
Beryllium |
| -- |
Radium |
| -- |
Fundamental Properties and the Network |
| -- |
Hydrides, Oxides, Hydroxides, and Halides |
| -- |
Uniqueness of Beryllium and Diagonal Relationship to Aluminum |
| -- |
Reactions and Compounds of Practical Importance |
| -- |
Beryllium Disease |
| -- |
Radiochemical Uses |
| -- |
Metallurgical Uses |
| -- |
Fireworks and X Rays |
| -- |
Hard Water |
| -- |
Selected Topic in Depth: The Commercial Uses of Calcium Compounds |
| -- |
CaCO3 (Limestone) |
| -- |
CaO (Quicklime) and Ca(OH)2 (Slaked Lime) |
| -- |
Summary |
| -- |
Problems |
| -- |
The Group 3A Elements |
| -- |
Discovery and Isolation of the Elements |
| -- |
Boron |
| -- |
Aluminum |
| -- |
Gallium |
| -- |
Indium and Thallium |
| -- |
Fundamental Properties and the Network |
| -- |
Hydrides, Oxides, Hydroxides, and Halides |
| -- |
Structural Aspects of Boron Chemistry |
| -- |
Allotropes |
| -- |
Borides |
| -- |
Borates |
| -- |
Aluminum, Gallium, Indium, and Thallium: Reactions and Compounds of Practical Importance |
| -- |
Aluminum Metal and Alloys |
| -- |
Alums |
| -- |
Alumina |
| -- |
Gallium, Indium, and Thallium Compounds |
| -- |
Selected Topic in Depth: Electron-Deficient Compounds |
| -- |
Summary |
| -- |
Problems |
| -- |
The Group 4A Elements |
| -- |
Discovery and Isolation of the Elements |
| -- |
Carbon, Tin, and Lead |
| -- |
Silicon |
| -- |
Germanium |
| -- |
Fundamental Properties and the Network |
| -- |
Hydrides |
| -- |
Oxides and Hydroxides |
| -- |
Halides |
| -- |
An Eighth Component of the Interconnected Network: pπ-dπ Bonding Involving Elements of the Second and Third Periods |
| -- |
Reactions and Compounds of Practical Importance |
| -- |
Diamond, Graphite, and the Graphenes |
| -- |
Tin Disease |
| -- |
Radiochemical Uses |
| -- |
Carbon Compounds |
| -- |
Lead Compounds and Toxicology |
| -- |
Silicates, Silica, and Aluminosilicates |
| -- |
Silicates and Silica |
| -- |
Aluminosilicates |
| -- |
Selected Topics in Depth: Semiconductors and Glass |
| -- |
Semiconductors |
| -- |
Glass |
| -- |
Summary |
| -- |
Problems |
| -- |
Group 5A: The Pnicogens |
| -- |
Discovery and Isolation of the Elements |
| -- |
Antimony and Arsenic |
| -- |
Phosphorus |
| -- |
Bismuth |
| -- |
Nitrogen |
| -- |
Fundamental Properties and the Network |
| -- |
The Uniqueness Principle |
| -- |
Pπ-dπ Bonding Involving Elements of the Second and Third Periods |
| -- |
Other Network Components |
| -- |
Hydrides |
| -- |
Oxides and Oxoacids |
| -- |
Halides |
| -- |
A Survey of Nitrogen Oxidation States |
| -- |
Nitrogen (-3) Compounds: Nitrides and Ammonia |
| -- |
Nitrogen (-2): Hydrazine, N2H4 |
| -- |
Nitrogen (-1): Hydroxylamine, NH2OH |
| -- |
Nitrogen (+1): Nitrous Oxide, N2O |
| -- |
Nitrogen (+2): Nitric Oxide, NO |
| -- |
Nitrogen (+3): Dinitrogen Trioxide, N2O3, and Nitrous Acid, HNO2 |
| -- |
Nitrogen (+4): Nitrogen Dioxide, NO2 |
| -- |
Nitrogen (+5): Dinitrogen Pentoxide, N2O5, and Nitric Acid, HNO3 |
| -- |
Reactions and Compounds of Practical Importance |
| -- |
Nitrogen Fixation |
| -- |
Nitrates and Nitrites |
| -- |
Nitrogen Air Bags |
| -- |
Matches and Phossy Jaw |
| -- |
Phosphates |
| -- |
Selected Topic in Depth: Photochemical Smog |
| -- |
Summary |
| -- |
Problems |
| -- |
Sulfur, Selenium, Tellurium, and Polonium |
| -- |
Discovery and Isolation of |
|
| Title |
the Elements |
| -- |
Sulfur |
| -- |
Tellurium and Selenium (Earth and Moon) |
| -- |
Polonium |
| -- |
Fundamental Properties and the Network |
| -- |
Hydrides |
| -- |
Oxides and Oxoacids |
| -- |
Halides |
| -- |
Allotropes and Compounds Involving Element-Element Bonds |
| -- |
Allotropes |
| -- |
Polycations and Anions |
| -- |
Catenated Halides and Hydrides |
| -- |
Catenated Oxoacids and Corresponding Salts |
| -- |
Sulfur Nitrides |
| -- |
Reactions and Compounds of Practical Importance |
| -- |
Sodium-Sulfur Batteries |
| -- |
Photoelectric Uses of Selenium and Tellurium |
| -- |
Sulfuric Acid |
| -- |
Selected Topic in Depth: Acid Rain |
| -- |
Summary |
| -- |
Problems |
| -- |
Group 7A: The Halogens |
| -- |
Discovery and Isolation of the Elements |
| -- |
Chlorine |
| -- |
Iodine |
| -- |
Bromine |
| -- |
Fluorine |
| -- |
Astatine |
| -- |
Fundamental Properties and the Network |
| -- |
Hydrides |
| -- |
Halides |
| -- |
Oxides |
| -- |
Oxoacids and Their Salts |
| -- |
Hypohalous Acids, HOX, and Hypohalites, OX- |
| -- |
Halous Acids, HOXO, and Halites, XO-2 |
| -- |
Halic Acids, HOXO2, and Halates, XO-3 |
| -- |
Perhalic Acids, HOXO3, and Perhalates, XO-4 |
| -- |
Neutral and Ionic Interhalogens |
| -- |
Reactions and Compounds of Practical Importance |
| -- |
Fluoridation |
| -- |
Chlorination |
| -- |
Bleaches |
| -- |
Bromides |
| -- |
Selected Topic in Depth: Chlorofluorocarbons (CFCs)-A Threat to the Ozone Layer |
| -- |
Summary |
| -- |
Problems |
| -- |
Group 8A: The Noble Gases |
| -- |
Discovery and Isolation of the Elements |
| -- |
Argon |
| -- |
Helium |
| -- |
Krypton, Neon, and Xenon |
| -- |
Radon |
| -- |
Fundamental Properties and the Network |
| -- |
Compounds of Noble Gases |
| -- |
History |
| -- |
Fluorides |
| -- |
Structures |
| -- |
Other Compounds |
| -- |
Physical Properties and Elements of Practical Importance |
| -- |
Selected Topic in Depth: Radon as a Carcinogen |
| -- |
Summary |
| -- |
Problems |
| -- |
A Word about Sources |
| -- |
Credit References |
| -- |
Lists of Figures, Tables, Formulas, and Constants |
| -- |
Index |
| 650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM |
| Topical term or geographic name as entry element |
Coordination compounds |
|
| Topical term or geographic name as entry element |
Solid state chemistry |
|
| Topical term or geographic name as entry element |
Chemistry, Inorganic |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) |
| Source of classification or shelving scheme |
Library of Congress Classification |
| Koha item type |
Kitap |